Semisynthetic ferulic acid derivative: an efficient feed additive for Genetically Improved Farmed Tilapia (Oreochromis niloticus)

Ferulic acid (FA) derivative was synthesized by modifying the functional groups of FA as dietary additive in the feeding of Genetically Improved Farmed Tilapia (GIFT) juveniles. Structural confirmation of this compound was based on IR, ¹H and ¹³C NMR techniques. This study was conducted to evaluate the effects of dietary FA derivative supplementation on growth performance, antioxidant status and serum biochemical parameters of GIFT juveniles compared with that of FA. A total of 675 fish with an average initial weight of 10.73 ± 0.40 g were fed nine diets supplemented with 0, 0.26, 0.52, 1.04 and 2.08 mmol kg^?1 FA, or 0.26, 0.52, 1.04 and 2.08 mmol kg^?1 FA derivative. Each diet was assigned to three replicate groups of 25 experimental tilapia for 56 days. Weight gain (WG) in groups of fish fed FA derivative was much higher than that of fish fed FA diet (P < 0.05). The antioxidant enzyme activities (SOD, CAT and GPx) in serum and liver of tilapia fed the FA derivative diets were significantly higher, while the malondialdehyde values were significantly lower than those of the fish fed the FA diets (P < 0.05). The serum biochemical parameters of GIFT were significantly improved by the FA derivative supplement. Moreover, feed conversion ratio, hepatosomatic index and viscerosomatic index were significantly decreased in fish fed FA or FA derivative diet at 0.52 mmol kg^?1 feed (P < 0.05). The investigation on the semisynthetic FA derivative provides a new way for developing safe and efficient feed additives.     

基于PLSR-BP复合模型的红壤有机质含量反演研究

对红壤地区土壤有机质进行快速预测,以满足智慧农业与精准施肥的需要。以江西省奉新县北部为研究区域,采用1 km×1 km标准格网划分研究区进行采样,共得到红壤样本248个。对土壤光谱进行了包含分数阶导数在内的3种数学变换方法,将经过P=0.01显著性检验的波段用于模型的构建,选用偏最小二乘回归(PLSR)和BP神经网络建立土壤有机质含量预测模型。结果表明:当对红壤光谱数据进行1.5阶导数变换后再使用PLSR-BP复合模型对土壤有机质含量进行预测时的结果为最优,训练集R~2=0.89,RMSE=4.68g·kg~(-1),验证集R~2=0.87,RMSE=5.55g·kg~(-1),RPD=2.75。1.5阶导数对红壤光谱数据的变换能够更好地突出与有机质相关的特征信息,有助于其含量预测。PLSR-BP复合模型预测精度优于单一模型,能够较好地预测红壤有机质含量,为精准农业快速监测红壤有机质含量提供了新的途径。     

液相色谱柱后衍生法快速测定马铃薯中10种氨基甲酸酯类农药残留

为了提高马铃薯氨基甲酸酯类农药残留检测效率，采用高效液相色谱柱后衍生法建立了马铃薯中10种氨基甲酸酯类农药的快速检测方法，并采用加标回收的方法测定回收率和精密度，以检验该方法的准确性和可靠性。结果表明：10种氨基甲酸酯农药回收率为77.1%～106.0%，相对标准偏差（RSDs） 为1.2%～6.7%，说明液相色谱柱后衍生法快速测定方法简单、快速、经济，可满足马铃薯中10种氨基甲酸酯类农药残留的检测工作。     

中的鞘氨醇类代谢产物

从中国香港红树林的两株南海海洋真菌(2526#和1850#)的代谢产物中分离到4个化合物，通过完整的波谱数据分别解析为鞘氨醇类化合物N-(2’，3‘-二羟基二十四碳酰基)-1，3-二羟基-2-氨基十八烷(A)、n-(2’，3‘-二羟基二十六碳酰基)-1，3-二羟基-2-氨基十八烷(B)、2‘-dehydroxycerebroside D(C)和cerebroside D(D)。化合物A和B未见文献报道。     

Initial shapes of stress-strain curve of wood specimen subjected to repeated combined compression and vibration stresses and the piezoelectric behavior

This study investigated the relationship between the initial shape of the stress (σ)-strain (ε) curve of a Chamaecyparis obtusa wood specimen subjected to repeated combined compression and vibration stresses at various angles between the fiber direction and load direction and the piezoelectric behavior. The main findings of the study are: (1) the σ-ε curve became convex initially, and then the stress was proportional to the strain. The σ-ε curve had almost the same shape during both loading and unloading. (2) The σ-piezoelectric voltage (P) curve was nonlinear, with a maximal point or cusp on the curve, which had almost the same shape during both loading and unloading, as was also observed for the σ-ε curve. (3) The plot of the first derivative of the stress [dσ/dε (= σ′)] against ε was nonlinear. The σ′-ε and P-ε curves at various angles were fairly similar. (4) The stress at the maximal point (or cusp) of the σ-P curve decreased with an increase in the angle between the fiber direction and load direction. The tendency of the stresses was very similar to that of Young’s modulus and compression strength calculated from Hook’s law and Hankinson’s law, respectively.     

The phytotoxicity of natural tetramic acid derivatives

Natural tetramic acid derivatives have attracted a great deal of interest of chemists because of their structural features and the broad range of biological activities. This paper focuses on five naturally occurring tetramic acid derivatives reported to have phytotoxicity and discusses their common structural characteristics. Copyright © 2011 Society of Chemical Industry     

公司治理、管理者动机与衍生金融工具使用

基于中国上市公司2007~2013年财务数据，研究公司治理对管理者使用衍生金融工具的影响，并结合中国制度背景，深入分析和检验企业产权、政策监管对公司治理效应的影响。实证结果表明，公司治理对管理者使用衍生金融工具的动机存在重要影响，公司治理水平越高，管理者越倾向于利用衍生金融工具避免财务困境风险；相反，管理者越倾向于利用衍生金融工具规避薪酬风险。研究还发现，公司治理的作用机制会受到所有权性质的影响，国有控制属性会弱化公司治理效应，对衍生金融工具交易的政策监管差异是重要原因。     

基于PID神经网络的滑翔增程制导炮弹解耦控制系统设计

采用Wiener空间的两个算子以及相关的恒等式，提出了新的方法证明了关于高斯过程函数的中心极限定理，并给出了该中心极限定理的应用实例.     

Optimality Conditions for Nonsmooth Extremum Problems in Topological Vector Spaces

Some new concepts of coneD_s convexity,coneD-s quasiconvexity,cone D-s pseudoconvexity,s right derivative of vector value mapping are proposed;and their related properties are discussed;the optimality necessary conditions and sufficient conditions for constrained extremum problem(VP)involving in cone D-s convex mapping are extablished;the relation between local optimal solution and global optimal solution;as well as the relation between weakly efficient solution and efficient solution for (VP) are derived;the corresponding results generalize the related results of classic convex programming.     

刚体平面运动的矢量导数解和矩阵解

一般而言,在理论力学的运动学中,平面运动刚体的平面图形上各点的速度与加速度的主要求解方法与计算公式,是应用运动的分解与合成─Ｃｈａｓｌｅ运动叠加定理导出的。本文作者应用矢量导数直接导出上述公式,并且在矢量导数的定型公式基础上建立相应的定型矩阵公式,使此类问题的求解简明便捷,又能应用矩阵的ＦＯＲＴＲＡＮ程序,使用日趋普及的现代化电脑进行运算。